
Natural pigments are derived from a variety of sources, including minerals, plants, and even insects. These pigments are coloured substances that can be ground, washed, and sifted to create paint. For example, yellow ochre is derived from the iron oxide mineral goethite and is used to create a yellow-brown pigment. While natural pigments are considered non-toxic, it's important to note that the term non-toxic is not highly regulated and is primarily a marketing term. Artists should still be cautious when working with pigments to avoid exposure to toxic dust. Synthetic pigments are also available and are commonly used in the paint industry, offering homogeneity in shape, size, and composition. These pigments are designed to be dispersed within the medium rather than dissolved, ensuring the particles remain locked in the paint once it dries.
| Characteristics | Values |
|---|---|
| Source of pigments | Natural sources such as minerals, plants, insects, and other organic sources. |
| Toxicity | "Non-toxic" is a marketing term with little regulation. It means the product is not poisonous and does not contain ingredients linked to toxic responses in humans. |
| Types of pigments | Organic (contain carbon) or inorganic. Organic pigments include azo pigments and copper phthalocyanines. Inorganic pigments include titanium dioxide, iron oxide, and ultramarine blue. |
| Particle size | Smaller particles increase the covering power of pigments and reduce colour nuances to the primary hue. |
| Transparency | Achieved by reducing pigment particle size and surrounding particles with a coating to prevent crystal growth. |
| Binder | Substance that holds pigment particles together and helps paint adhere to a surface. |
| Oil absorption | The amount of oil required to bind a pigment into paint. |
| Opacity | Degree to which a paint covers the surface beneath it. |
| Corrosion inhibition | Some pigments can help prevent corrosion by physically obstructing water and oxygen and providing protective films. |
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What You'll Learn
- Natural pigments are derived from minerals, plants, and insects
- Organic pigments are made from carbon, hydrogen, oxygen, and nitrogen
- Inorganic pigments are made from simple chemical reactions or found naturally as earths
- Titanium dioxide is an important inorganic pigment
- Cadmium-free colours are a popular non-toxic alternative for artists

Natural pigments are derived from minerals, plants, and insects
Minerals are a common source of natural pigments. Ochre, for example, is a term used for pigments derived from iron oxides and iron-based minerals, clays, and soils. These are common minerals found worldwide that contain varying amounts of iron and oxygen. The natural pigment yellow ochre is derived from the iron oxide mineral goethite. To prepare mineral pigments, the rocks are broken into small pieces and ground into a fine powder using a mortar and pestle.
Plants are another primary source of natural pigments. Betalains, for instance, are a group of pigmented compounds prevalent in plants of the order Caryophyllales, as well as some species of fungi and bacteria. They play a pivotal role in the vivid colours observed in the fruits, flowers, and stems of diverse plant species. Plant melanins are derived from monophenolic precursors and exhibit a wide range of diversity and complexity.
Insects also provide natural pigments. Carmine, a bright red pigment, is obtained from the aluminium complex derived from carminic acid, which is extracted from some scale insects such as the cochineal scale and certain Porphyrophora species. Cochineal nests can be found on Opuntia ficus-indica host cacti. To prepare carmine, the powdered insect bodies are boiled in an ammonia or sodium carbonate solution.
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Organic pigments are made from carbon, hydrogen, oxygen, and nitrogen
Organic pigments are synthetic pigments that do not occur naturally. They are made from carbon, hydrogen, oxygen, and nitrogen, and sometimes other atoms such as phosphorus or sulphur. They are characterized by small particle size with high surface areas and are generally translucent. They range from poor to very good heat stability and light stability and are usually considered less toxic than heavy metal pigments.
The first organic pigments were harvested from nature as natural plant or animal products. Organic pigments include azo pigments, which contain a nitrogen group and account for most organic red, orange, and yellow pigments. Copper phthalocyanines provide strong blues and greens that are unusually colourfast for organic colours. Some pigments, such as fluorescent ones, are simply dyes that have been rendered insoluble by chemical reaction.
Organic pigments can be hard to disperse and tend to form clumps of pigment particles, which cause spots and specks in the product. They are applied in the form of discrete crystalline particles well dispersed in the medium. They are quite intense in colour but are much more stable due to their attachment to an inorganic salt. They also have a high tint strength and yield clean colour shades.
Organic pigments are used in paints, coatings, and inks, imparting colour, bulk, and desired physical and chemical properties to the wet or dry film. They are also used in inks, required to have high transparency, and in printing ink pigments.
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Inorganic pigments are made from simple chemical reactions or found naturally as earths
Inorganic pigments are an important class of substances that have been used by humans for thousands of years. They are used to colour other materials and are applied as finely ground solid particles mixed with a liquid.
Inorganic pigments are made from simple chemical reactions, such as precipitation and solid-state reactions at high temperatures. For special pigments, crystallization processes from molten salts, hydrothermal reactions, and gas-phase processes are used. For example, Prussian blue, a widely used blue pigment, is made through a chemical reaction between iron and cyanide.
Inorganic pigments can also be found naturally on Earth, such as clay earth pigments, which are naturally formed iron oxides. Raw umber, a natural clay pigment, is made up of iron oxide, manganese oxide, and aluminium oxide. When heated, it becomes burnt umber and has more intense colours. Raw sienna is another example of a naturally occurring yellow-brown pigment from limonite clay. Iron-oxide earth pigments yield ochres (yellow-browns), siennas (orange-browns), and umbers (browns). Ultramarine violet is another example of a naturally occurring inorganic pigment.
Natural pigments are derived from sources such as minerals, plants, and insects. For example, the natural pigment yellow ochre is derived from the iron oxide mineral goethite found in many locations on Earth. The mineral is ground into small particles, washed, and sifted but remains chemically unaltered.
Inorganic pigments are generally more stable against the influence of light, temperature, chemicals, and atmospheres than organic pigments.
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Titanium dioxide is an important inorganic pigment
Titanium dioxide (TiO2) is an inorganic compound with the chemical formula TiO2. It is derived from the elemental metal titanium and is a versatile compound that is a white solid that is insoluble in water. This feature, combined with its high opacity and brightness, makes it an ideal choice for use as a pigment in paints.
TiO2 is an important pigment in paints, coatings, and inks. It is used to impart colour, bulk, and desired physical and chemical properties to the wet or dry film. Titanium dioxide is particularly good at providing whiteness and opacity to paints. This is due to its high refractive index, which allows it to bend and scatter light effectively. The refractive index of titanium dioxide is even higher than that of a diamond.
TiO2 particles of the right size scatter visible light with a wavelength of λ ≈ 380 - 700 nm, contributing to its high opacity. The opacity of titanium dioxide can be adjusted by varying the particle size, with smaller particles resulting in higher transparency. This makes titanium dioxide useful for creating metallic finishes, as well as for printing ink pigments that require high transparency.
Titanium dioxide has been used as a pigment in paints for nearly a century, and it is considered to be non-toxic and safe for use in many applications, including paints and cosmetics. However, it is important to handle it with care, especially in its powdered form, to avoid inhaling the dust. Regulatory bodies in some countries have restricted its use in food products and other ingestible items due to concerns over potential inhalation toxicity.
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Cadmium-free colours are a popular non-toxic alternative for artists
Artists have long been drawn to cadmium pigments for their intensely bright, lightfast results. However, cadmium is a heavy metal, and while there is no global consensus, some concerns have been raised about its safety. As a result, artists are increasingly turning to cadmium-free colours, which offer a non-toxic alternative without compromising on quality or performance.
Winsor & Newton, for instance, has developed cadmium-free colours that identically match the colour of genuine cadmium and behave in the same way. These colours have been independently tested and certified as safe to use by the Art and Creative Materials Institute (ACMI). Similarly, Utrecht has introduced a range of cadmium-free oils and acrylics that perform just as well as their cadmium-containing counterparts, offering artists a healthier and more environmentally responsible choice.
In a blind test conducted by Dick Blick, artists were asked to compare the tone, tint, and opacity of cadmium-free colours to their cadmium counterparts. The results showed that, in addition to having fewer health and environmental concerns, the cadmium-free paints equalled or even exceeded the quality and performance of the natural cadmium colours. This is achieved by making the particles as small as possible to increase the covering power of the pigments.
While the availability of cadmium-free colours is a positive development, it is important to note that the term "non-toxic" in the context of pigments is primarily restricted to the product's intended application and may not apply to all possible uses. For instance, a pigment may be considered non-toxic in an artist's paint but not in cosmetics or food. Therefore, it is crucial for artists to always determine the intended use of a pigment before selecting it for their work.
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Frequently asked questions
Pigments are insoluble and are applied as finely ground solid particles mixed with a liquid. They impart colour, bulk, and desired physical and chemical properties to the wet or dry film.
Non-toxic pigments are formulated to be safe for human use. They are made to replace historic toxic pigments. The term "non-toxic" is mostly a marketing term with little regulation. It means the product is not poisonous or doesn't contain ingredients linked to toxic responses like hormone disruption or cancer.
Natural pigments are derived from minerals, plants, and insects. They may be ground, washed, and sifted but are not chemically modified. For example, yellow ochre is derived from the iron oxide mineral goethite and is simply ground into small particles.
Ochres, siennas, and umbers are non-toxic pigments derived from iron oxides and iron-based minerals, clays, and soils. Cadmium-free colours are another popular non-toxic alternative for artists.
Non-toxic pigments are safer for human use and the environment. They can also provide a transformative journey that fosters a harmonious bond between oneself and the Earth, rekindling our inner essence and senses.











































